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Abstract. Ground-based instruments offer unique capabilities such as detailed atmospheric, thermodynamic, cloud, and aerosol profiling at a high temporal sampling rate. The U.S. Department of Energy Atmospheric Radiation Measurement (ARM) user facility provides comprehensive datasets from key locations around the globe, facilitating long-term characterization and process-level understanding of clouds, aerosol, and aerosol–cloud interactions. However, as with other ground-based datasets, the fixed (Eulerian) nature of these measurements often introduces a knowledge gap in relating those observations with air-mass hysteresis. Here, we describe ARMTRAJ (https://doi.org/10.5439/2309851, Silber, 2024a; https://doi.org/10.5439/2309849, Silber, 2024b; https://doi.org/10.5439/2309850, Silber, 2024c; https://doi.org/10.5439/2309848, Silber, 2024d), a set of multipurpose trajectory datasets that helps close this gap in ARM deployments. Each dataset targets a different aspect of atmospheric research, including the analysis of surface, planetary boundary layer, distinct liquid-bearing cloud layers, and (primary) cloud decks. Trajectories are calculated using the Hybrid Single-Particle Lagrangian Integrated Trajectory (HYSPLIT) model informed by the European Centre for Medium-Range Weather Forecasts ERA5 reanalysis dataset at its highest spatial resolution (0.25°) and are initialized using ARM datasets. The trajectory datasets include information about air-mass coordinates and state variables extracted from ERA5 before and after the ARM site overpass. Ensemble runs generated for each model initialization enhance trajectory consistency, while ensemble variability serves as a valuable uncertainty metric for those reported air-mass coordinates and state variables. Following the description of dataset processing and structure, we demonstrate applications of ARMTRAJ to a case study and a few bulk analyses of observations collected during ARM's Eastern Pacific Cloud Aerosol Precipitation Experiment (EPCAPE) field deployment. ARMTRAJ will soon become a near real-time product accompanying new ARM deployments and an augmenting product to ongoing and previous deployments, promoting reaching science goals of research relying on ARM observations. 

Data availability pending. The Arctic is warming faster than any other place on Earth, with sea ice declining rapidly and sources of sea spray and biogenic aerosol emissions changing by consequence. Utqiagvik is at the forefront of this change, abutting one of the largest areas of sea ice loss. This change will have far-reaching impacts to both the environment and the community. Because this change has happened largely in the last decade, now is an important time to both document that change and to continue a data record that will allow for a characterization of the New Arctic, as climate is already altering the Arctic landscape forever. The longest and most complete record of aerosol properties in the American Arctic is that of Utqiagvik, making this unique location serve as a regional record of changes in atmospheric aerosol properties. This dataset will extend the baseline measurements of this Arctic aerosol record, including and continuing the 15-year record of submicron inorganic components (Quinn et al., 2009; Quinn et al., 2002), re-instituting the 2-year record of organic components collected a decade ago (Frossard et al., 2011; Shaw et al., 2010), enhancing the chemical analysis with sulfur isotopes to improve interpretation of emission sources (Kunasek et al., 2010; Thiemens & Lin, 2019), continuing particle number size distribution measurements (Freud et al., 2017), and re-starting cloud condensation nuclei measurements (Schmale, Henning, et al., 2018). 

### Access Dataset and extensive metadata can be accessed and downloaded from the 'ADC' directory via: [http://arcticdata.io/data/10.18739/A2X05XF2D](http://arcticdata.io/data/10.18739/A2X05XF2D) ### Overview The Arctic is warming faster than any other place on Earth, with sea ice declining rapidly and sources of sea spray and biogenic aerosol emissions changing by consequence. Utqiagvik is at the forefront of this change, abutting one of the largest areas of sea ice loss. This change will have far-reaching impacts to both the environment and the community. Because this change has happened largely in the last decade, now is an important time to both document that change and to continue a data record that will allow for a characterization of the New Arctic, as climate is already altering the Arctic landscape forever. The longest and most complete record of aerosol properties in the American Arctic is that of Utqiagvik, making this unique location serve as a regional record of changes in atmospheric aerosol properties. This dataset will extend the baseline measurements of this Arctic aerosol record, including and continuing the 15-year record of submicron inorganic components (Quinn et al., 2009; Quinn et al., 2002), re-instituting the 2-year record of organic components collected a decade ago (Frossard et al., 2011; Shaw et al., 2010), enhancing the chemical analysis with sulfur isotopes to improve interpretation of emission sources (Kunasek et al., 2010; Thiemens & Lin, 2019), continuing particle number size distribution measurements (Freud et al., 2017), and re-starting cloud condensation nuclei measurements (Schmale, Henning, et al., 2018). 

### Access Dataset can be accessed and downloaded from the 'ADC' directory via: [http://arcticdata.io/data/10.18739/A2X63B701](http://arcticdata.io/data/10.18739/A2X63B701) ### Overview The Arctic is warming faster than any other place on Earth, with sea ice declining rapidly and sources of sea spray and biogenic aerosol emissions changing by consequence. Utqiagvik is at the forefront of this change, abutting one of the largest areas of sea ice loss. This change will have far-reaching impacts to both the environment and the community. Because this change has happened largely in the last decade, now is an important time to both document that change and to continue a data record that will allow for a characterization of the New Arctic, as climate is already altering the Arctic landscape forever. The longest and most complete record of aerosol properties in the American Arctic is that of Utqiagvik, making this unique location serve as a regional record of changes in atmospheric aerosol properties. This dataset will extend the baseline measurements of this Arctic aerosol record, including and continuing the 15-year record of submicron inorganic components (Quinn et al., 2009; Quinn et al., 2002), re-instituting the 2-year record of organic components collected a decade ago (Frossard et al., 2011; Shaw et al., 2010), enhancing the chemical analysis with sulfur isotopes to improve interpretation of emission sources (Kunasek et al., 2010; Thiemens & Lin, 2019), continuing particle number size distribution measurements (Freud et al., 2017), and re-starting cloud condensation nuclei measurements (Schmale, Henning, et al., 2018). 

These measurements are provided by a differential mobility analyzer operated as a scanning mobility particle sizer, a printed particle optical spectrometer (POPS), and a continuous flow diffusion cloud condensation nuclei (CCN) counter. The instruments sample from either a counterflow virtual impactor inlet or an isokinetic inlet. The measurements provide the mobility aerosol size distribution (30-360 nm), optical size distribution (150 - 6000 nm), size-resolved CCN distribution (30-360 nm) at 0.2, 0.4, 0.6, 0.8, and 1.0% supersaturation. CCN measurements are performed in denuded and undenuded configuration, where denuded refers to the removal of low molecular weight organic vapors. A detailed NetCDF header is included with the datafiles. Users of these measurements are encouraged to consult with the authors about appropriate interpretation before submitting for publication, offering coauthorship where appropriate. 

Marine cloud brightening (MCB) is the deliberate injection of aerosol particles into shallow marine clouds to increase their reflection of solar radiation and reduce the amount of energy absorbed by the climate system. From the physical science perspective, the consensus of a broad international group of scientists is that the viability of MCB will ultimately depend on whether observations and models can robustly assess the scale-up of local-to-global brightening in today’s climate and identify strategies that will ensure an equitable geographical distribution of the benefits and risks associated with projected regional changes in temperature and precipitation. To address the physical science knowledge gaps required to assess the societal implications of MCB, we propose a substantial and targeted program of research—field and laboratory experiments, monitoring, and numerical modeling across a range of scales. 

This dataset includes aerosol microphysics and chemical measurements collected at Mt. Soledad and Scripps Pier during the Eastern Pacific Cloud Aerosol Precipitation Experiment (EPCAPE) from February 2023 to February 2024. The measurements include the following instruments at Mt. Soledad: High-Resolution Time-of-Flight Aerosol Mass Spectrometer (HR-ToF-AMS, Aerodyne), Scanning Electrical Mobility Spectrometer (SEMS, Brechtel Manufacturing Inc.), Aerodynamic Particle Sizer (APS, Droplet Measurements Technologies), Single Particle Soot Photometer (SP2, Drople Measurements Technologies), Meteorological Station (WXT520, Vaisala), Ozone (Teco), and trace gas proxies (Teledyne). In addition, the analyses of particle filters collected at Mt. Soledad for three dry-diameter size cuts (<1 micron, <0.5 micron, <0.18 micron) and at Scripps Pier for one dry-diametr size cut (<1 micron) by Fourier Transform Infrared (FTIR) and X-ray Fluorescence (XRF) are reported. A differential mobility analyzer operated as a scanning mobility particle sizer (SMPS, TSI Inc.), a printed particle optical spectrometer (POPS, Grimm), and a continuous flow diffusion cloud condensation nuclei (CCN, DMT) counter provide the mobility aerosol size distribution (30-360 nm), optical size distribution (150 - 6000 nm), size-resolved CCN distribution (30-360 nm) at 0.2, 0.4, 0.6, 0.8, and 1.0% supersaturation. Measurements are reported for both sampling from an isokinetic aerosol inlet and from a Counterflow Virtual Impactor (CVI, Brechtel Manufacturing Inc.). Users of these measurements are encouraged to consult with the authors about appropriate interpretation before submitting for publication, offering coauthorship where appropriate. 

Abstract. Long-range transport of biogenic emissions from the coastof Antarctica, precipitation scavenging, and cloud processing are the mainprocesses that influence the observed variability in Southern Ocean (SO)marine boundary layer (MBL) condensation nuclei (CN) and cloud condensationnuclei (CCN) concentrations during the austral summer. Airborne particlemeasurements on the HIAPER GV from north–south transects between Hobart,Tasmania, and 62∘ S during the Southern Ocean Clouds, RadiationAerosol Transport Experimental Study (SOCRATES) were separated into fourregimes comprising combinations of high and low concentrations of CCN andCN. In 5 d HYSPLIT back trajectories, air parcels with elevated CCNconcentrations were almost always shown to have crossed the Antarctic coast,a location with elevated phytoplankton emissions relative to the rest of theSO in the region south of Australia. The presence of high CCN concentrationswas also consistent with high cloud fractions over their trajectory,suggesting there was substantial growth of biogenically formed particlesthrough cloud processing. Cases with low cloud fraction, due to the presenceof cumulus clouds, had high CN concentrations, consistent with previouslyreported new particle formation in cumulus outflow regions. Measurementsassociated with elevated precipitation during the previous 1.5 d of theirtrajectory had low CCN concentrations indicating CCN were effectivelyscavenged by precipitation. A coarse-mode fitting algorithm was used todetermine the primary marine aerosol (PMA) contribution, which accounted for<20 % of CCN (at 0.3 % supersaturation) and cloud dropletnumber concentrations. Vertical profiles of CN and large particleconcentrations (Dp>0.07 µm) indicated that particleformation occurs more frequently above the MBL; however, the growth ofrecently formed particles typically occurs in the MBL, consistent with cloudprocessing and the condensation of volatile compound oxidation products. CCN measurements on the R/V Investigator as part of the second Clouds, Aerosols,Precipitation, Radiation and atmospheric Composition Over the southeRn Ocean(CAPRICORN-2) campaign were also conducted during the same period as theSOCRATES study. The R/V Investigator observed elevated CCN concentrations near Australia,likely due to continental and coastal biogenic emissions. The Antarcticcoastal source of CCN from the south, CCN sources from the midlatitudes, andenhanced precipitation sink in the cyclonic circulation between the Ferreland polar cells (around 60∘ S) create opposing latitudinalgradients in the CCN concentration with an observed minimum in the SObetween 55 and 60∘ S. The SOCRATES airbornemeasurements are not influenced by Australian continental emissions butstill show evidence of elevated CCN concentrations to the south of60∘ S, consistent with biogenic coastal emissions. In addition, alatitudinal gradient in the particle composition, south of the Australianand Tasmanian coasts, is apparent in aerosol hygroscopicity derived from CCNspectra and aerosol particle size distribution. The particles are morehygroscopic to the north, consistent with a greater fraction of sea saltfrom PMA, and less hygroscopic to the south as there is more sulfate andorganic particles originating from biogenic sources in coastal Antarctica. 

Abstract. Observations of the organic components of the natural aerosol are scarce in Antarctica, which limits our understanding of natural aerosols and their connection to seasonal and spatial patterns of cloud albedo in the region. From November 2015 to December 2016, the ARM West Antarctic Radiation Experiment (AWARE) measured submicron aerosol properties near McMurdo Station at the southern tip of Ross Island. Submicron organic mass (OM), particle number, and cloud condensation nuclei concentrations were higher in summer than other seasons. The measurements included a range of compositions and concentrations that likely reflected both local anthropogenic emissions and natural background sources. We isolated the natural organic components by separating a natural factor and a local combustion factor. The natural OM was 150 times higher in summer than in winter. The local anthropogenic emissions were not hygroscopic and had little contribution to the CCN concentrations. Natural sources that included marine sea spray and seabird emissions contributed 56% OM in summer but only 3% in winter. The natural OM had high hydroxyl group fraction (55%), 6% alkane, and 6% amine group mass, consistent with marine organic composition. In addition, the Fourier transform infrared (FTIR) spectra showed the natural sources of organic aerosol were characterized by amide group absorption, which may be from seabird populations. Carboxylic acid group contributions were high in summer and associated with natural sources, likely forming by secondary reactions.